Ingredient review

Iron Oxides (Black)

INCI: CI 77499

A safe, non-irritating mineral pigment that provides black color in makeup and skincare.

beautyskincarecolorant

In plain English

CI 77499 is a black iron oxide pigment. It's a mineral that's ground into a fine powder and used to give color to makeup and skincare products. Think of it as the ingredient that makes black eyeliner black or darkens a foundation shade. It's very stable, doesn't fade easily, and is generally considered safe and non-irritating for most people.

Review score

Safety, usefulness, and evidence

4.5Excellent
4.5/ 5

Strong fit for many routines

The evidence base is relatively strong for its common cosmetic role.

Risk flags are low for most users, though the finished product can still irritate.

Source
natural
Evidence
strong
Irritation
low
Clogging risk
low
How reviews are scored

Quick decision guide

Easy yes for most routines

Iron Oxides (Black) is generally a lower-concern ingredient when the full formula suits your skin.

Plain-English read

Treat this as a practical screening step before you compare products that contain this ingredient.

  1. Step 1Start with the score, then check the irritation and clogging risk before judging Iron Oxides (Black).
  2. Step 2Use the "Best for" and "Use caution if" sections to match the ingredient to your skin, not just to a marketing claim.
  3. Step 3If a product stings, breaks you out, or worsens irritation, judge the finished formula and stop using it even if the ingredient scores well.

Score terms in plain English

Irritation risk

low

Less likely to sting, burn, or bother most users, though sensitive skin can still react.

Clogging risk

low

Less likely to feel heavy or contribute to clogged pores for most skin types.

Evidence level

strong

There is a stronger practical or research basis for the ingredient role described here.

What it is

CI 77499 is a synthetic or natural iron oxide pigment that produces a black color. It is part of a family of iron oxides (including red, yellow, and brown) commonly used in cosmetics. It is approved by the FDA for use in cosmetics and is considered a safe color additive.

How it works

As a pigment, CI 77499 works by reflecting and absorbing light to create a black color. When mixed into a product, it disperses evenly to provide consistent color coverage. It does not chemically react with the skin; instead, it sits on the surface to impart color.

Pros

Very safe for sensitive skin

Iron oxides are among the least irritating colorants and are approved by the FDA for use in cosmetics, including around the eyes.

Color stays true and doesn't fade

Unlike some organic dyes, iron oxides are light-stable and heat-stable, so your makeup color won't change or fade quickly.

Cons and cautions

Can be messy if not formulated well

If the pigment isn't properly dispersed, it can leave black streaks or stains on clothes or skin.

Limited to opaque shades

Because it's a pigment, it creates opaque colors and isn't suitable for sheer or translucent finishes.

Best for

  • Anyone looking for a safe, non-irritating black pigment in makeup
  • People with sensitive skin who want a gentle colorant

Use caution if

  • Those with known allergies to iron oxides (very rare)

Usage tips

Check the ingredient list for 'CI 77499' if you want a black pigment that's less likely to irritate than carbon black.
If you're prone to staining, use a setting spray or powder to lock in the pigment.
For a natural look, look for products that blend iron oxides with other pigments for a more skin-like finish.

Safety summary

CI 77499 is one of the safest colorants in cosmetics. It is non-toxic, non-irritating, and non-sensitizing for the vast majority of people. It is approved by the FDA and other global regulators for use in all types of cosmetics, including those applied near the eyes.

Research notes

Iron oxides have been extensively studied and are considered safe for cosmetic use. The Cosmetic Ingredient Review (CIR) panel has concluded that iron oxides are safe as used in cosmetics. No significant health concerns have been identified.

Common label clues

Typical concentration
0.1% to 10% depending on desired shade
Regulatory status
Approved by the FDA as a color additive for cosmetics, including use around the eyes. Also approved by the EU and other major regulators.
Common uses
Foundations, Concealers, Eyeliners, Mascaras, Lipsticks, Blushes, Pressed Powders
Environmental note
Iron oxides are naturally occurring minerals and are generally considered environmentally safe. Mining and processing can have environmental impacts, but synthetic versions are also available.

Good to know

  • CI 77499 is often combined with other iron oxides (CI 77491 red, CI 77492 yellow) to create a wide range of skin tones.
  • It is considered a 'clean' colorant by many natural beauty standards because it is a mineral and not a synthetic dye.

Common questions

What is Iron Oxides (Black) in beauty products?

CI 77499 is a black iron oxide pigment. It's a mineral that's ground into a fine powder and used to give color to makeup and skincare products. Think of it as the ingredient that makes black eyeliner black or darkens a foundation shade. It's very stable, doesn't fade easily, and is generally considered safe and non-irritating for most people.

What does Iron Oxides (Black) do in a beauty product?

As a pigment, CI 77499 works by reflecting and absorbing light to create a black color. When mixed into a product, it disperses evenly to provide consistent color coverage. It does not chemically react with the skin; instead, it sits on the surface to impart color.

Is Iron Oxides (Black) safe for most people?

CI 77499 is one of the safest colorants in cosmetics. It is non-toxic, non-irritating, and non-sensitizing for the vast majority of people. It is approved by the FDA and other global regulators for use in all types of cosmetics, including those applied near the eyes.

Who should be careful with Iron Oxides (Black)?

Those with known allergies to iron oxides (very rare)

Research sources

Ingredient reviews are educational and are not medical advice. Patch test new products and ask a licensed clinician about persistent irritation, allergies, pregnancy-specific questions, or diagnosed skin conditions.