Ingredient review

Iron Oxide (Black)

INCI: CI 77489

A safe, non-irritating black mineral pigment that adds color to makeup and skincare without clogging pores.

beautyskincarecolorant

In plain English

CI 77489 is a black iron oxide pigment. It's a natural mineral that's ground into a fine powder and used to give color to makeup like foundation, eyeliner, and lipstick. It's very stable, doesn't fade easily, and is considered safe for most skin types, including sensitive skin.

Review score

Safety, usefulness, and evidence

4.5Excellent
4.5/ 5

Strong fit for many routines

The evidence base is relatively strong for its common cosmetic role.

Risk flags are low for most users, though the finished product can still irritate.

Source
natural
Evidence
strong
Irritation
low
Clogging risk
low
How reviews are scored

Quick decision guide

Easy yes for most routines

Iron Oxide (Black) is generally a lower-concern ingredient when the full formula suits your skin.

Plain-English read

Treat this as a practical screening step before you compare products that contain this ingredient.

  1. Step 1Start with the score, then check the irritation and clogging risk before judging Iron Oxide (Black).
  2. Step 2Use the "Best for" and "Use caution if" sections to match the ingredient to your skin, not just to a marketing claim.
  3. Step 3If a product stings, breaks you out, or worsens irritation, judge the finished formula and stop using it even if the ingredient scores well.

Score terms in plain English

Irritation risk

low

Less likely to sting, burn, or bother most users, though sensitive skin can still react.

Clogging risk

low

Less likely to feel heavy or contribute to clogged pores for most skin types.

Evidence level

strong

There is a stronger practical or research basis for the ingredient role described here.

What it is

A black iron oxide (FeO·Fe₂O₃) pigment, a naturally occurring mineral that is mined and processed for use in cosmetics. It is one of several iron oxides approved for use as colorants in personal care products.

How it works

It works by physically reflecting and absorbing light to create a black color. When dispersed in a product's base (like a cream or powder), it tints the formula to achieve the desired shade. It does not chemically react with the skin.

Pros

Very safe for skin

Iron oxides are among the most thoroughly tested and safest colorants used in cosmetics. They rarely cause irritation or allergic reactions, even on sensitive skin.

Does not clog pores

Unlike some organic pigments, iron oxides are non-comedogenic, meaning they won't block pores or contribute to breakouts. This makes them ideal for foundations and concealers for acne-prone skin.

Cons and cautions

Can stain fabrics

Because it's a fine, intense black powder, it can easily transfer and stain clothing, towels, or bedding if not set properly with powder or a setting spray.

May leave a temporary tint on skin

If not thoroughly removed with a good cleanser or makeup remover, the pigment can leave a faint gray or black residue on the skin, especially around the eyes.

Best for

  • Anyone looking for a safe, non-irritating black pigment in makeup
  • People with sensitive or acne-prone skin who want color without irritation

Use caution if

  • Those with a known allergy to iron oxides (extremely rare)
  • People who prefer only plant-based colorants (iron oxides are mineral)

Usage tips

Always remove makeup thoroughly with an oil-based cleanser or micellar water to avoid any pigment residue.
Set liquid or cream products containing this pigment with a translucent powder to minimize transfer.
Patch test a new product on your inner arm before using it on your face, especially if you have very sensitive skin.

Safety summary

CI 77489 (black iron oxide) is considered one of the safest cosmetic colorants. It has a very low potential for irritation, sensitization, or toxicity. Regulatory bodies worldwide approve its use in all types of cosmetics, including those for the eye area.

Research notes

Extensive safety reviews by the Cosmetic Ingredient Review (CIR) panel and the European Chemicals Agency (ECHA) have concluded that iron oxides are safe for use in cosmetics at current concentrations. No significant health risks have been identified.

Common label clues

Typical concentration
0.1% to 5% or more, depending on desired shade depth
Regulatory status
Approved as a color additive for cosmetics in the US (FDA), EU (EC), and many other countries. It is listed under CI 77489 in the EU CosIng database and is generally recognized as safe for use in all cosmetic products, including those applied around the eyes.
Common uses
Foundations, Concealers, Eyeliners, Mascaras, Lipsticks, Blushes, Pressed powders
Environmental note
Iron oxides are naturally abundant minerals. Mining and processing have some environmental impact, but they are not considered persistent pollutants and are generally safe for aquatic life at typical cosmetic concentrations.

Good to know

  • CI 77489 is one of several iron oxide colorants approved by the FDA for use in cosmetics (including around the eyes).
  • It is often combined with other iron oxides (yellow, red) to create a wide range of skin-tone shades.
  • Unlike some black pigments derived from coal tar, iron oxides are mineral-based and considered very safe.

Common questions

What is Iron Oxide (Black) in beauty products?

CI 77489 is a black iron oxide pigment. It's a natural mineral that's ground into a fine powder and used to give color to makeup like foundation, eyeliner, and lipstick. It's very stable, doesn't fade easily, and is considered safe for most skin types, including sensitive skin.

What does Iron Oxide (Black) do in a beauty product?

It works by physically reflecting and absorbing light to create a black color. When dispersed in a product's base (like a cream or powder), it tints the formula to achieve the desired shade. It does not chemically react with the skin.

Is Iron Oxide (Black) safe for most people?

CI 77489 (black iron oxide) is considered one of the safest cosmetic colorants. It has a very low potential for irritation, sensitization, or toxicity. Regulatory bodies worldwide approve its use in all types of cosmetics, including those for the eye area.

Who should be careful with Iron Oxide (Black)?

Those with a known allergy to iron oxides (extremely rare) People who prefer only plant-based colorants (iron oxides are mineral)

Research sources

Ingredient reviews are educational and are not medical advice. Patch test new products and ask a licensed clinician about persistent irritation, allergies, pregnancy-specific questions, or diagnosed skin conditions.