Ingredient review

Di-HEMA Trimethylhexyl Dicarbamate

INCI: Di-HEMA Trimethylhexyl Dicarbamate

A synthetic film-former that helps makeup last longer and resist smudging, but may be drying for some users.

beautycosmeticsfilm-former

In plain English

This is a man-made ingredient that creates a flexible, waterproof film on your skin or nails. It's what helps your lipstick stay put through meals and your mascara not run in the rain. Think of it like a clear, invisible glue that holds makeup pigments in place. Because it forms a tight film, it can feel a bit stiff or drying on the lips or around the eyes, especially if you have dry skin.

Review score

Safety, usefulness, and evidence

3.5Good
3.5/ 5

Potentially useful with some tradeoffs

The evidence base is useful, but some claims depend heavily on the formula.

Risk flags are low for most users, though the finished product can still irritate.

Source
synthetic
Evidence
moderate
Irritation
low
Clogging risk
low
How reviews are scored

Quick decision guide

Useful, but context matters

Di-HEMA Trimethylhexyl Dicarbamate is generally a lower-concern ingredient when the full formula suits your skin.

Plain-English read

Treat this as a practical screening step before you compare products that contain this ingredient.

  1. Step 1Start with the score, then check the irritation and clogging risk before judging Di-HEMA Trimethylhexyl Dicarbamate.
  2. Step 2Use the "Best for" and "Use caution if" sections to match the ingredient to your skin, not just to a marketing claim.
  3. Step 3If a product stings, breaks you out, or worsens irritation, judge the finished formula and stop using it even if the ingredient scores well.

Score terms in plain English

Irritation risk

low

Less likely to sting, burn, or bother most users, though sensitive skin can still react.

Clogging risk

low

Less likely to feel heavy or contribute to clogged pores for most skin types.

Evidence level

moderate

There is useful support, but formula details and claim strength still matter.

What it is

Di-HEMA Trimethylhexyl Dicarbamate is a synthetic polymer created by reacting HEMA (hydroxyethyl methacrylate) with a dicarbamate compound. It is designed to form a flexible, durable film on the skin or nails, making it a popular ingredient in long-wear and waterproof cosmetics.

How it works

When applied, the ingredient's molecules link together as the solvent evaporates, forming a continuous, flexible film. This film physically locks pigments and other ingredients onto the surface of the skin, nail, or lash, resisting transfer to clothing or other surfaces and providing water and sweat resistance.

Pros

Exceptional staying power

Creates a durable film that keeps makeup in place for hours, resisting transfer to cups, clothes, or skin.

Water and sweat resistant

The film repels moisture, making it ideal for humid conditions, workouts, or tear-prone eyes.

Cons and cautions

Can be drying

The tight film can pull moisture from the lips or eyelids, leading to a parched or uncomfortable feel over time.

Requires special removal

Because it's so tenacious, water-based cleansers often won't remove it; you'll need an oil-based or balm cleanser to break down the film.

Best for

  • Anyone wanting long-wear lipstick or mascara that lasts through eating and humidity
  • People with oily eyelids who need eyeliner or shadow that won't smudge

Use caution if

  • Those with very dry or sensitive lips who find long-wear formulas uncomfortable

Usage tips

Apply a hydrating lip balm or eye cream before using long-wear products containing this ingredient to minimize dryness.
Remove with an oil-based makeup remover or cleansing balm to avoid rubbing and irritation.
Avoid layering too many film-forming products on the same area to prevent a stiff, cakey feel.

Safety summary

Di-HEMA Trimethylhexyl Dicarbamate is considered safe for use in cosmetics at typical concentrations. It has low irritation and comedogenic potential. However, because it forms a tight film, it may cause dryness or discomfort for those with sensitive or dry skin, especially on the lips. Always remove thoroughly with an oil-based cleanser to avoid buildup.

Research notes

Safety assessments by the Cosmetic Ingredient Review (CIR) panel and EU authorities have concluded that this ingredient is safe for use in leave-on and rinse-off cosmetics. Studies focus on its film-forming properties rather than skin absorption, as its large molecular size limits penetration. No significant toxicity or sensitization concerns have been reported in published literature.

Common label clues

Typical concentration
Typically 1-10% in leave-on products
Regulatory status
Approved for use in cosmetics in the US, EU, and other major markets. The EU CosIng database lists it as a film-forming agent with no specific restrictions at typical use levels.
Common uses
Long-wear lipsticks, Liquid lipsticks, Nail polishes, Mascaras, Eyeliners
Environmental note
As a synthetic polymer, it is not biodegradable and may persist in the environment. Some brands are moving toward bio-based film-formers, but this ingredient remains widely used for its performance.

Good to know

  • This ingredient is chemically related to HEMA, a common monomer in nail acrylics, but is polymerized and considered safe for cosmetic use.
  • It is often combined with emollients and oils in the formula to balance its drying effect.

Common questions

What is Di-HEMA Trimethylhexyl Dicarbamate in beauty products?

This is a man-made ingredient that creates a flexible, waterproof film on your skin or nails. It's what helps your lipstick stay put through meals and your mascara not run in the rain. Think of it like a clear, invisible glue that holds makeup pigments in place. Because it forms a tight film, it can feel a bit stiff or drying on the lips or around the eyes, especially if you have dry skin.

What does Di-HEMA Trimethylhexyl Dicarbamate do in a beauty product?

When applied, the ingredient's molecules link together as the solvent evaporates, forming a continuous, flexible film. This film physically locks pigments and other ingredients onto the surface of the skin, nail, or lash, resisting transfer to clothing or other surfaces and providing water and sweat resistance.

Is Di-HEMA Trimethylhexyl Dicarbamate safe for most people?

Di-HEMA Trimethylhexyl Dicarbamate is considered safe for use in cosmetics at typical concentrations. It has low irritation and comedogenic potential. However, because it forms a tight film, it may cause dryness or discomfort for those with sensitive or dry skin, especially on the lips. Always remove thoroughly with an oil-based cleanser to avoid buildup.

Who should be careful with Di-HEMA Trimethylhexyl Dicarbamate?

Those with very dry or sensitive lips who find long-wear formulas uncomfortable

Research sources

Ingredient reviews are educational and are not medical advice. Patch test new products and ask a licensed clinician about persistent irritation, allergies, pregnancy-specific questions, or diagnosed skin conditions.